• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to cleaning compositions comprising at least one combination of special preservatives. In addition, the present invention relates to the use of the cleaning compositions according to the invention for the cleaning and / or care of the skin and / or the hair, as well as the use of a certain combination of preserving agents for the preservation of surfactant cleaning compositions.
    公开号:FR3044900A1
    申请号:FR1661839
    申请日:2016-12-02
    公开日:2017-06-16
    发明作者:Heike Schelges；Rainer Simmering；Barbara Heide；Melanie Rauschenberg
    申请人:Henkel AG and Co KGaA；
    IPC主号:
    专利说明:

    The present invention relates to cleaning agent compositions which contain, in addition to at least one surfactant, at least one special combination of preservatives and at least one additional preservative. The aforementioned cleaning agents have an exceptional cleaning effect and at the same time good preservation.
    In addition, the present invention relates to the use of the cleaning composition according to the invention for cleaning and care of the skin and / or hair.
    Because of their composition, the cosmetic agents can serve as a nutrient medium for germs and microorganisms. These germs can, on the one hand, cause microbial contamination of the consumer, on the other hand, they can modify the ingredients of cosmetics and thus form substances causing undesirable effects such as sensitivity or skin irritation. To avoid these unwanted consequences and to ensure a certain minimum duration of use of cosmetics, they must be kept. But since preservatives possess an irritating potential, their use in cosmetics is strictly regulated.
    The microflora of the skin has a determining influence on different cosmetic parameters. Thus, pathogenic germs such as Staphylococcus aureus play a decisive role in the formation of cutaneous impurities. The latest studies also reveal that unbalanced skin microflora can affect skin aging because undesirable germs can lead to increased immune defense of the skin, which in turn increases inflammatory responses in which aging markers of the skin are stimulated.
    There is therefore still a need for preservative compositions that prevent colonization of the product or the skin by undesirable germs on the one hand and, on the other hand, that do not disturb or substantially disturb the natural flora of the skin. .
    The mixture of different antimicrobial substances to enhance the antimicrobial activity is in principle known. Thus, WO 03/043 593 A1 proposes to combine traditional antibacterial substances such as triclosan, phenoxyethanol or hexetidine with lauric ethyl arginate to enhance the antibacterial effect. Patent WO 2007/014580 A1 proposes mixtures of preserving agents which contain, in addition to lauric ethyl arginate, salts of organic and inorganic acids, in particular sodium citrate, sodium acetate and glutamate. Sodium fumarate, sodium malate, sodium gluconate, sodium laurate, sodium lactate, sodium hexametaphosphate, sodium t-butyl hydroquinone, sodium propyl parahydroxybenzoate or sodium glucosamine hydrochloride or ethanolamine. Cosmetic compositions which contain a mixture of preservatives based on lauryl ethyl arginate and parabens, imidazolidinyl urea, phenoxyethanol, hydantoin DMDM, 2-methyl-5-chloro-3,4-isothiazolinone / 2-methyl-3,4-isothiazolinone and quaternium-15 are disclosed in EP 1414394 B1.
    It is therefore necessary to develop antimicrobial compositions that are very effective in small quantities.
    The present invention therefore aimed to prepare cleaning compositions having an exceptional cleaning and caring effect and, at the same time, good preservation. In particular, it was necessary to find synergistic preservative mixtures which are very effective at low concentrations and which allow the manufacture of cleaning compositions causing little irritation or sensitivity because of the amounts used overall reduced. In addition, no preservatives perceived as critical by the consumer should be used. In addition, the quality and quantity of the foam should not be adversely affected by the addition of the preservative mixture.
    Surprisingly, it has been discovered that the use of certain preservative blends in surfactant cleaning compositions results in a synergistic effect with respect to the preservative effect. This makes it possible to reduce the amount of preservatives used without having a negative impact on the preservative effect. Due to the reduced amount of preservatives, the cleaning compositions of the invention cause little irritation and sensitivity. In addition, the addition of blends of preservatives improves the quality and quantity of foam. The object of the present invention is therefore a cleaning composition, comprising in a cosmetically acceptable support a) at least one surfactant chosen from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, and mixtures of these and b) at least one mixture of preserving agents selected from the group consisting of chloroxylenol and phenoxyisopranol undecylenic acid and formic acid phenoxyisopropanol and piroctone-olamine phenoxyisopranol and formic acid a or more than one sulfite and hexetidine phenoxyisopranol and formic acid lauric ethyl arginate and chloroxylenol hexetidine and benzyl alcohol hexetidine and chloroxylenol hexetidine and piroctone olamine hexetidine and chlorhephenine hexetidine and formic acid, and mixtures thereof, and c) at least one additional preservative selected from in the group consisting of benzoic acid and its salts, propanoic acid and its salts, salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide , phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts, and mixtures of these preservatives.
    According to the invention, the term "mixture of preserving agents" is understood to mean a mixture consisting of two preservatives previously mentioned in characteristic b).
    The percentage by weight refers here, and unless otherwise indicated, to the total weight of the cleaning composition according to the invention, the total of all the ingredients of the agent according to the invention being equal to 100% by weight.
    The first main ingredient a) that comprises the cleaning composition according to the invention is at least one surfactant selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, and mixtures thereof.
    The term "surfactant" is intended to mean amphipatic (bifunctional) compounds according to the invention, which consist of at least one part of hydrophobic molecule and at least one part of hydrophilic molecule. The hydrophobic residue is preferably a hydrocarbon chain comprising 8 to 28 carbon atoms and which may be saturated or unsaturated, linear or branched. In a particularly preferred manner, this C8-C28 alkyl chain is linear.
    By anionic surfactants is meant surfactants comprising exclusively anionic fillers. The surfactants in question preferably comprise at least one carboxyl group and / or a sulfonic acid group and / or a sulfate group. In the context of the present invention, it has been found preferable that the cleaning compositions comprise at least one determined anionic surfactant. Preferred cleaning compositions according to the present invention are therefore characterized in that the cosmetic agents comprise at least one anionic surfactant derived from the group comprising (i) alkyl (alkyl) ether sulphates having 8 to 18 carbon atoms in the chain alkyl, and 0 or 1 to 6 ethylene oxide units, (ii) C12-C18 alkyl ether carboxylates, (iii) C12-C18 acylated isethionate, (iv) C12 acylated sarcosinate; C18, (v) C12-C18 acyltaurine, and (vi) mixtures thereof.
    Cationic surfactants are understood to mean, according to the invention, surfactants comprising exclusively cationic fillers. The surfactants in question comprise at least one quaternary ammonium group. According to the invention, it is preferable to use certain cationic surfactants. It is therefore advantageous in the context of the present invention that they contain at least one cationic surfactant from the group comprising (i) quaternized carboxylic acid ester salts with triethanolamine, (ii) quaternized acid salts. carboxylic acid with diethanolalkylamine, (iii) quaternized carboxylic acid salts with 1,2-dihydroxypropyldialkylamine, (iv) Quaternium-92, (v) C10-C22 alkyltrimethylammonium chloride, and (vi) mixtures thereof.
    The amphoteric surfactants are divided into ampholytic surfactants and zwitterionic surfactants. Ampholytic surfactants are understood to mean surface-active compounds having both acid groups (for example -COOH or -SO 3 H groups) and basic hydrophilic groups (for example amino groups) and which behave in an acidic or basic manner according to conditions. By zwitterionic surfactants, one skilled in the art hears surfactants carrying both a negative charge and a positive charge in the same molecule. According to the invention, the use of certain amphoteric surfactants has proved advantageous. Preferred cleaning compositions according to the present invention are therefore characterized in that they comprise at least one amphoteric surfactant from the group consisting of (i) (C 10 -C 18) alkylbetaines, (ii) (C 8-12) alkylamido (C 1 -C) alkyl-betaines, (iii) (C 10 -C 18) alkyl-sulfobetaines (iv) (C 10 -C 18) alkyl-amphoacetates and (C 10 -C 18) alkyl-amphodiacetates; -Ci8) alkyl-amphopropionates and (Cio-C18) alkyl-dipropionates, as well as (vi) mixtures thereof.
    By nonionic surfactants is meant according to the invention surfactants having no charged group. The term "charged groups" is intended to mean both cationic and anionic groups as well as temporarily cationic and anionic groups. The permanently cationic and anionic groups have a cationic or anionic charge irrespective of the pH value. On the contrary, the temporarily cationic and anionic groups only have a cationic or anionic charge at certain pH values. According to the invention, it is preferred that the cleaning composition comprises at least one nonionic surfactant from the group consisting of (i) C10-C18 alkyl polyglucosides, (ii) sorbitan esters and sorbitan ether esters. (iii) C10-C18 carboxylic acid monoethanolamides; (iv) C10-C18 alcohol ethoxylates having 2 to 40 moles of ethylene oxide and / or propylene oxide per mole of alcohol, (v) C10-C18 amine oxides, (vi) glyceryl cocoates having 2 to 40 moles of ethylene oxide and / or propylene oxide per mole of glyceryl cocoate, and (vii) mixtures thereof.
    Advantageously, the at least one surfactant in the cleaning compositions according to the invention is used in certain quantitative ranges. Preferred cleaning compositions according to the present invention are therefore characterized in that they comprise, based on their total weight, 0.5 to 60% by weight, preferably 1.0 to 50% by weight, more preferably 1 to 50% by weight. 5 to 40% by weight, particularly preferably 2.0 to 30% by weight of at least one surfactant selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants and mixtures thereof. The use of the aforementioned amounts guarantees a sufficient cleaning effect, foam quality and foam quantity. In addition, these amounts do not have a negative influence on the preservative effect of the combination of preservatives.
    The cleaning compositions according to the invention comprise, as the second main ingredient b), at least a certain mixture of preserving agents. These mixtures of preserving agents have a synergistic effect with respect to the antimicrobial effect and therefore result in a particularly effective preservation of the cleaning compositions according to the invention. In addition, the amount used can be reduced by this synergistic effect, which allows to obtain cleaning compositions causing little irritation and sensitivity. In addition, the use of the preservative mixture improves the quality and quantity of foam.
    The cleaning compositions according to the invention preferably have a certain weight ratio between the preserving agents included in this cleaning composition. In the context of the present invention, it is preferred that the cleaning composition has a weight ratio of the first preservative to the second preservative in the preservative mixture b) of 10: 1 to 1:10, preferably 8: 1 to 1: 8, more preferably 5: 1 to 1: 5, more preferably 2: 1 to 1: 2. The use of these weight ratios has been found to be particularly advantageous with respect to synergistic increase in the effectiveness of the preservatives of this mixture. The cleaning agent according to the invention contains the mixture of preservatives, preferably in certain quantitative ranges. Preferred cleaning compositions according to the invention are therefore characterized in that they comprise, based on their total weight, 0.001 to 10% by weight, preferably 0.005 to 7.0% by weight, more preferably 0.01% by weight. to 4.0% by weight, particularly preferably 0.05 to 2.0% by weight of at least one mixture of preservatives b). The amounts given above relate to the total amount of the preservative mixture, i.e. the mixture of the two preservatives mentioned above. The use of said amounts of mixture of preservatives results in exceptional preservation of the cleaning compositions according to the invention. In addition, it is possible to reduce the amount used due to the synergistic effect of the preservative mixture without adversely affecting the preservative power. The cleaning compositions according to the invention thus cause particularly little irritation and sensitivity.
    The third main ingredient contained in the cleaning compositions according to the invention is at least one additional preservative agent c) chosen from the group comprising benzoic acid and its salts, propanoic acid and its salts, salicylic acid and its salts. salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts, and mixtures of these preservatives. The addition of this at least one additional preservative entails, in connection with the aforementioned combination of preserving agents, a synergistic increase in the conservation power.
    However, it may be preferred to use, in the context of the present invention, a mixture of the aforementioned compounds as preservative c). Preferred cleaning compositions according to the invention are therefore characterized in that they comprise at least one additional preservative agent c) chosen from the group comprising benzoic acid and its salts, propanoic acid and its salts, salicylic acid. and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts. Other preferred cleaning compositions according to the invention are characterized in that they comprise at least two additional preserving agents c) selected from the group comprising benzoic acid and its salts, propanoic acid and its salts, the acid salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts.
    In addition, advantageous cleaning compositions according to the invention are those comprising at least three additional preserving agents c) chosen from the group comprising benzoic acid and its salts, propanoic acid and its salts, salicylic acid and its salts. salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts.
    Finally, cleaning compositions according to the invention comprising, as additional preservative c), a mixture of benzoic acid and its salts, propanoic acid and its salts, salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral and acid citric.
    In a particularly preferred manner, the cleaning compositions according to the invention comprise, as additional preservative agent c), the preserving agents mentioned in the table on pages 7 to 10 of the priority document or mixtures of these preserving agents KM1 to KM466.
    In this context, it is advantageous for the at least one additional preservative agent c) to be used in a certain total amount. It is therefore preferred according to the invention that the cosmetic agents comprise, based on their total weight, 0.001 to 10% by weight, preferably 0.005 to 9.0% by weight, more preferably 0.05 to 8.0% by weight. by weight, particularly preferably 0.1 to 7.0% by weight of at least one additional preservative c). If more than one additional preservative (c) is used, the above-mentioned total amounts relate to the mixture of these preservatives. The use of said amounts of the at least one additional preservative causes, in combination with the at least one mixture of preservatives b), a synergistic increase in the conservation power.
    The table on pages 11 to 25 of the priority document indicates particularly preferred embodiments AF1 to AF579 of the cosmetic agents according to the invention (all the data are expressed in% by weight). In this table, c corresponds to chloroxylenol, p to phenoxyisopropanol, u to undecylenic acid, to formic acid, pi to piroctone-olamine, s to sulfite, h to hexetidine, e to arginate, ethyl lauric * HCl, chlorphenesin, benzyl alcohol, anionic surfactant AnionT, cationic surfactant KationT, nonionic surfactant nioT and amphoteric surfactant amphoT. In the table, the indication (c + p) (1: 2) thus represents a mixture of chloroxylenol and phenoxyisopropanol in a ratio by weight of 1: 2 (relative to the total weight of the mixture). (c + p) + (u + a) represents the combination of a mixture of chloroxylenol and phenoxyisopropanol and a mixture of undecylenic acid and formic acid. AnionT + KationT represents, according to this logic, a mixture of an anonic surfactant and an amphoteric surfactant. The aforementioned preservatives or KM1 to KM466 preservative mixtures are used as additional preservative c) (referred to as KM in the table).
    In embodiments AF1 to AF579, the surfactants used are preferably the aforementioned anionic, cationic, amphoteric and nonionic surfactants. The cosmetic agents AF1 to AF579 have a good cleaning effect and exceptional preservation. Thanks to the synergistic effect of the preservatives used, it is possible to reduce the amount of these agents without having a negative effect on the preservative effect. The cosmetic compositions according to the invention thus cause particularly little irritation and sensitivity. In addition, the use of the aforementioned preservative mixture can improve the quality and quantity of the foam, so that its use does not exert a negative influence on the cleaning properties.
    In addition to the components a) to c) mandatory according to the invention, the cleaning compositions according to the invention can in principle use all the other components known to those skilled in the art for cosmetic compositions of this type. Other active ingredients, excipients and additives may for example be mentioned: thickeners such as gelatin or the natural gum, for example agar-agar, guar gum, alginate, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextran, cellulose derivatives such as methylcellulose, hydroxyalkylcellulose or carboxymethylcellulose, fractions and starch derivatives such as amylose, amylopectin or dextrin, fully synthetic hydrocolloids such as polyvinyl alcohol, structuring agents such as maleic acid or lactic acid, solvents and solubilizing agents such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerine or diethylene glycol, - active ingredients improving the fibrous structure, especially mono-, di- and oligosaccharides such as glucose, galactose, fructose dare, fruit sugar, or lactose, - dyes for coloring the product, - pH-modifying substances, such as, for example, α- and β-carboxylic acids, - active ingredients such as allantoin or bisabolol; complexing agents such as EDTA, NTA, β-alanine-diacetic acid and phosphonic acids; ceramides. By ceramides is meant N-acylsphingosine (sphingosine fatty acid amide) or synthetic analogues of these lipids (so-called "pseudo-ceramides"), opacifying agents, such as latex, copolymers of styrene and PVP, and styrene and acrylamide, - pearlescent agents such as ethylene glycol monostearate and distearate or PEG-3 distearate, - pigments, - propellants such as mixtures of propane-butane, N2O, dimethyl ether, CO 2 or air, viscosity regulators such as salts (NaCl), cationic, nonionic and amphoteric polymers, vitamins, especially groups A, B, C, E, F and H, UV filters, in particular benzophenone, p-aminobenzoic acid AmphoT, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazole and o-aminobenzoic acid esters, protein hydrolysates and cationic protein hydrolysates, humectants or penetration adjuvants and / or blowing agents, especially urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water-soluble glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycol ethers, propylene glycol ethers, for example propylene glycol monomethyl ether, carbonate, hydrogen carbonate, 1,2-benzene, diols and 1,3-diols, plant extracts, such as green tea, white tea, oak bark, nettle, hamamelis, hops, chamomile, burdock roots, horsetail, hawthorn, linden flowers, lychee, almond, aloe vera, spruce needles, horse chestnut, sandalwood, juniper, coconut, mango , apricot, lime, wheat, kiwi, melon, orange, grape, sage, rosemary, birch u, mallow, meadow cardamen, wild thyme, yarrow, thyme, lemon balm, spiny bush, coltsfoot, marshmallow, ginseng, ginger roots, echinacea purpurea, olea europea, common fennel or celery, silicone oils, in particular polyalkylsiloxanes, polyarylsiloxanes or polyalkylarylsiloxanes, which may be optionally functionalized with organic groups and / or ethoxy groups and / or propoxy groups.
    The other ingredients mentioned above may be present, based on the total weight of the cleaning composition, in a total amount of 0.001 to 50% by weight, preferably 0.01 to 40% by weight, more preferably 0.1 30% by weight, particularly preferably from 0.5 to 20% by weight.
    Finally, a second object of the present invention is the use of a cleaning composition according to the invention for cleaning and care and skin and hair.
    With regard to other preferred embodiments of the process according to the invention, in particular with regard to the cleaning compositions which are used therein, what has been exposed to the cleaning compositions according to the invention applies mutatis mutandis.
    Regarding other embodiments of the use according to the invention, what has been exposed on the cleaning composition according to the invention applies mutatis mutandis.
    The following examples explain the present invention without limiting its scope:
    Examples:
    The cleaning compositions mentioned below have been manufactured:
    Shower gel (data expressed in% by weight)
    Mixture of preserving agents chosen from at least one of the above-mentioned preservative mixtures KM1 to 466
    Liquid soap (data expressed in% by weight)
    1) Blend of preservatives selected from at least one of the aforementioned preservative mixtures KM1 to 466
    Washing gel (data in% by weight)
    Ί) Mixture of preserving agents selected from at least one of the above-mentioned preservative mixtures KM1 to 466
    Washing gel (data in% by weight)
    1) Blend of preservatives selected from at least one of the aforementioned preservative mixtures KM1 to 466
    Washing cream (data expressed in
    % in weight)
    1) Blend of preservatives selected from at least one of the aforementioned preservative mixtures KM1 to 466
    Shower gel (data expressed in% by weight)
    Mixture of preserving agents chosen from at least one of the above-mentioned preservative mixtures KM1 to 466
    Cleaner (data expressed in% by weight)
    Mixture of preservatives selected from at least one of the above-mentioned preservative mixtures KM1 to 466
    Lotion for the face (data expressed in% by weight)
    Mixture of preservatives selected from at least one of the above-mentioned preservative mixtures KM1 to 466
    Shower cream (data expressed in% by weight)
    1) Blend of preservatives selected from at least one of the aforementioned preservative mixtures KM1 to 466
    权利要求:
    Claims (14)
    [1" id="c-fr-0001]
    claims
    A cleaning composition comprising in a cosmetically acceptable carrier a) at least one surfactant selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, and mixtures thereof and b) at least one a mixture of preservatives selected from the group consisting of chloroxylenol and phenoxyisopranol undecylenic acid and formic acid phenoxyisopropanol and piroctone-olamine phenoxyisopranol and formic acid one or more sulfites and hexetidine the lauric ethyl arginate and formic acid lauric ethyl arginate and chloroxylenol hexetidine and benzyl alcohol hexetidine and chloroxylenol hexetidine and piroctone-olamine hexetidine and chlorphenesine hexetidine and formic acid and mixtures thereof, and c) at least one additional preservative selected from the group consisting of benzoic acid that, and its salts, propanoic acid and its salts, salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts, and mixtures of these preservatives.
    [2" id="c-fr-0002]
    2. Cleaning composition according to claim 1, characterized in that it comprises, relative to its total weight, 0.5 to 60% by weight, preferably 1.0 to 50% by weight, more preferably 1.5. at 40% by weight, more preferably 2.0 to 30% by weight of at least one surfactant, selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants and them.
    [3" id="c-fr-0003]
    3. Cleaning composition according to one of claims 1 or 2 characterized in that it comprises at least one anionic surfactant from the group comprising (i) alkyl sulfates (ether) having 8 to 18 carbon atoms in the chain alkyl, and 0 or 1 to 6 ethylene oxide units, (ii) C12-C18 alkyl ether carboxylates, (iii) C12-C18 acylated isethionate, (iv) C12 acylated sarcosinate, C18, (v) C12-C18 acyltaurine, and (vi) mixtures thereof.
    [4" id="c-fr-0004]
    4. Cleaning composition according to any one of the preceding claims, characterized in that it comprises a cationic surfactant from the group comprising (i) salts of quaternized esters of carboxylic acid with triethanolamine, (ii) quaternized salts carboxylic acid with diethanolalkylamine, (iii) quaternized carboxylic acid salts with 1,2-dihydroxypropyldialkylamine, (iv) Quaternium-92, (v) C10-C22 alkyltrimethylammonium chloride, and (vi) mixtures thereof.
    [5" id="c-fr-0005]
    5. Cleaning composition according to any one of the preceding claims, characterized in that it comprises at least one amphoteric surfactant from the group comprising (i) (Cio-C18) alkyl-betaines, (ii) (C8.i2) alkyl-amido (C 1-4) alkyl-betaines, (iii) (C 10 -C 18) alkyl-sulfobetaines, (iv) (C 10 -C 18) alkyl-amphoacetates and (C 10 -C 18) alkyl-amphodiacetates, ) (C10-C18) alkyl-amphopropionates and (C10-C18) alkyl-dipropionates, as well as (vi) mixtures thereof.
    [6" id="c-fr-0006]
    6. Cleaning composition according to any one of the preceding claims, characterized in that it comprises at least one nonionic surfactant from the group comprising (i) C10-C18 alkyl polyglucosides, (ii) sorbitan esters and esters. of sorbitan ether, (iii) C10-C18 carboxylic acid monoethanolamides, (iv) C10-C18 alcohol ethoxylates having 2 to 40 moles of ethylene oxide and / or proprylene per mole of alcohol, (v) C10-C18 oxide amines, (vi) glyceryl cocoates containing 2 to 40 moles of ethylene oxide and / or propylene oxide per mole of glyceryl cocoate as well as (vii) mixtures thereof.
    [7" id="c-fr-0007]
    7. Cleaning composition according to any one of the preceding claims characterized in that it has a weight ratio of the first preservative to the second preservative in the mixture of preservatives c) from 10 to 1: 10, preferably from 8: 1 to 1: 8, more preferably from 5: 1 to 1: 5, particularly preferably from 2: 1 to 1: 2.
    [8" id="c-fr-0008]
    8. Cleaning composition according to any one of the preceding claims characterized in that it comprises, relative to its total weight, 0.001 to 10% by weight, preferably 0.005 to 7.0% by weight, more preferably 0 From 0.1 to 4.0% by weight, particularly preferably from 0.05 to 2.0% by weight of at least one mixture of preserving agents b).
    [9" id="c-fr-0009]
    9. Cleaning composition according to any one of the preceding claims, characterized in that it comprises at least one additional preservative agent c) selected from the group comprising benzoic acid and its salts, propanoic acid and its salts, and salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts.
    [10" id="c-fr-0010]
    10. Cleaning composition according to any one of the preceding claims, characterized in that it comprises at least two additional preservatives c) selected from the group comprising benzoic acid and its salts, propanoic acid and its salts, the salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts.
    [11" id="c-fr-0011]
    11. Cleaning composition according to any one of the preceding claims, characterized in that it comprises at least two additional preserving agents c) selected from the group comprising benzoic acid and its salts, propanoic acid and its salts, the salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, quaternary ammonium compounds, glutaral, citric acid and its salts.
    [12" id="c-fr-0012]
    12. Cleaning composition according to any one of the preceding claims characterized in that it comprises, as additional preservative c), a mixture of benzoic acid and its salts, propanoic acid and its salts, acid salicylic acid and its salts, sorbic acid and its salts, zinc salts, one or more parabens, polyaminopropyl biguanide, phenoxyethanol, climbazole, chlorhexidine and its salts, ammonium compounds quaternary, glutaral and citric acid.
    [13" id="c-fr-0013]
    13. Cleaning composition according to any one of the preceding claims, characterized in that it comprises, relative to its total weight, 0.001 to 10% by weight, preferably 0.005 to 9.0% by weight, more preferably 0 From 0.05 to 8.0% by weight, particularly preferably from 0.1 to 7.0% by weight of at least one additional preservative c).
    [14" id="c-fr-0014]
    14. Use of at least one preservative mixture selected from the group consisting of chloroxylenol and phenoxyisopropanol, undecylenic acid and formic acid, phenoxyisopranol and piroctone-olamine, phenoxyisopropanol and formic acid, one or more sulphites and hexetidine, lauric ethyl arginate and formic acid, lauryl ethyl arginate and chloroxylenol, hexetidine and benzyl alcohol, hexetidine and chloroxylenol, hexetidine and piroctone-olamine, hexetidine and chlorphenesin, hexetidine and formic acid, and mixtures thereof, for preserving surface-active cleaning compositions.
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    EP2331211A2|2011-06-15|Anti-dandruff and anti-relapse shampoo
    FR3045329A1|2017-06-23|
    FR3040877A1|2017-03-17|
    EP1066822B1|2004-10-06|Composition for treating dandruffs in hair and scalp based on an antidandruff agent and a hydroxy-acid
    FR3070859A1|2019-03-15|CLEANING AGENT BASED ON MICELLES TECHNOLOGY
    EP2359800B1|2018-09-12|Composition for cosmetic treatment of keratin fibres comprising volatile linear alkanes, C8-30 fatty alcohols and mono- or polyglycosides
    FR3040298A1|2017-03-03|POWERFUL CAPILLARY TREATMENT AGENT CONTAINING AN OLIGOPEPTIDE AND A MAGNESIUM SALT
    FR3012956A1|2015-05-15|COMPOSITION COMPRISING GLYCEROL AND GLYCINE
    FR3110407A1|2021-11-26|"Natural cosmetic cleaning agents containing propanediol caprylate"
    FR3102673A1|2021-05-07|Nourishing and creamy shower cream
    WO2021105339A1|2021-06-03|Shampoo veterinary compositions
    FR3113597A1|2022-03-04|Natural cosmetic cleansing agent
    FR3044895A1|2017-06-16|
    同族专利:
    公开号 | 公开日
    GB2553158A|2018-02-28|
    FR3044900B1|2020-05-01|
    US20170165169A1|2017-06-15|
    DE102015225004A1|2017-06-14|
    GB201620944D0|2017-01-25|
    US10357442B2|2019-07-23|
    GB2553158B|2020-07-15|
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    AT433663T|2001-08-09|2009-07-15|Miret Lab|NEW CONSERVATION SYSTEMS AND THEIR USE IN COSMETIC MEANS|
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    EP3574760A1|2018-05-30|2019-12-04|The Boots Company PLC|Cosmetic preservative system|
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    WO2021144272A1|2020-01-17|2021-07-22|Unilever Ip Holdings B.V.|Hair treatment composition|
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    US20210309948A1|2020-04-01|2021-10-07|Henkel IP & Holding GmbH|Unit Dose Detergent Pack Including A Liquid Detergent Composition With Improved Color Stability|
    法律状态:
    2017-12-21| PLFP| Fee payment|Year of fee payment: 2 |
    2018-12-20| PLFP| Fee payment|Year of fee payment: 3 |
    2019-08-09| PLSC| Publication of the preliminary search report|Effective date: 20190809 |
    2019-12-19| PLFP| Fee payment|Year of fee payment: 4 |
    2020-12-23| PLFP| Fee payment|Year of fee payment: 5 |
    2021-12-24| PLFP| Fee payment|Year of fee payment: 6 |
    优先权:
    申请号 | 申请日 | 专利标题
    DE102015225004.0|2015-12-11|
    DE102015225004.0A|DE102015225004A1|2015-12-11|2015-12-11|Surfactant-containing cleaning agents with at least three different preservatives|
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